Acetate and phosphate anion adsorption linear sweep voltammograms simulated using density functional theory

Specific adsorption of anions to electrode surfaces may alter the rates of electrocatalytic reactions. Density functional theory (DFT) methods are used to predict the adsorption free energy of acetate and phosphate anions as a function of Pt(1 1 1) electrode potential. Four models of the electrode potential are used including a simple vacuum slab model, an applied electric field model with and without the inclusion of a solvating water bi-layer, and the double reference model. The linear sweep voltammogram (LSV) due to anion adsorption is simulated using the DFT results. The inclusion of solvation at the electrochemical interface is necessary for accurately predicting the adsorption peak position. The Langmuir model is sufficient for predicting the adsorption peak shape, indicating coverage effects are minor in altering the LSV for acetate and phosphate adsorption. Anion adsorption peak positions are determined for solution phase anion concentrations present in microbial fuel cells and microbial electrolysis cells and discussion is provided as to the impact of anion adsorption on oxygen reduction and hydrogen evolution reaction rates in these devices.     

Topology optimization for the seismic design of truss-like structures

A practical optimization method is applied to design nonlinear truss-like structures subjected to seismic excitation. To achieve minimum weight design, inefficient material is gradually shifted from strong parts to weak parts of a structure until a state of uniform deformation prevails. By considering different truss structures, effects of seismic excitation, target ductility and buckling of the compression members on optimum topology are investigated. It is shown that the proposed method could lead to 60% less structural weight compared to optimization methods based on elastic behavior and equivalent static loads, and is efficient at controlling performance parameters under a design earthquake.     

Study on the Hydrogenated Diamond-Like Carbon Films Synthesized by RF-PECVD from n-decane

Using a mixture of n-decane and hydrogen, diamond-like carbon thin films (DLCTFs) with high growth rate of 35?nm/min are deposited by radio frequency plasma enhanced chemical vapor deposition. We show that n-decane can be considered as a promising carbon source in DLCTF deposition. The properties of the deposited films such as structure, hydrogen content, deposition rate and refractive index are studied for 20, 50 and 100?sccm hydrogen flow rates (HFRs). It is shown that the deposition rate has a maximum of 35?nm/min for HFR?=?20?sccm and by increasing hydrogen concentration, deposition rate drops to 19?nm/min for HFR?=?100?sccm. The Raman spectra reveal that the films represent hydrogenated diamond-like carbon features. The photoluminescence background of the Raman spectra is used as a measure for hydrogen content of the films. The hydrogen content varies from 29 to 46% which yields a various amount of sp³ fraction. The results of the spectroscopic ellipsometry indicate that by increasing HFR, refractive index decreases from 2.1 to 1.9 at 632?nm. The aforementioned trends are attributed to the increase of hydrogen content in DLCTFs which is in very good agreement with enhancing of the photoluminescence background of the Raman spectra.     

Optimal contract design for effort-averse sensors

ABSTRACT

A central planner wishes to engage a collection of sensors to measure a quantity. Each sensor seeks to trade-off the effort it invests to obtain and report a measurement, against contracted reward. Assuming that measurement quality improves as a sensor increases the effort it invests, the problem of the reward contract design is investigated. To this end, a game is formulated between the central planner and the sensors. Using this game, it is established that the central planner can enhance the quality of the estimate by rewarding each sensor based on the distance between the average of the received measurements and the measurement provided by the sensor. Optimal contracts are designed from the perspective of the budget required to achieve a specified level of error performance.     

Maximizing the Firm Energy Yield Preserving Total Energy Generation Via an Optimal Reservoir Operation

As specified from the marketing standpoint, firm hydro-electrical energy must be available on an assured basis. To achieve the firm energy yield at maximum level, simultaneous optimization of operational variables is utilized. The variables include reservoir releases over historical stream-inflow records as well as the plant factor. Here, the plant factor denotes the percentage of day for operating a peak-time power plant at full capacity. To this end, a differential evaluation (DE) algorithm equipped with an indirect constraint handling is employed, in which an adaptive penalty system imposes the desirable reliability and preserves the total energy generation. To implement the model for a real example, a reservoir dam named Karun4, in southwest of Iran, is applied. The experimental results show the firm energy produced by the current and developed method are 49.2 and 127.5 (10⁹ watt hours), respectively. Also, the results reveal the maximum capability of generating the firm energy yield with target reliability whereas the total energy generation is preserving.     

Neck,shoulder and low back pain in secondary schoolchildren in relation to schoolbag carriage: Should the recommended weight limits be gender-specific?

The occurrence of neck, shoulder and low back complaints in relation to schoolbag carriage and other potential risk factors were investigated in a cross-sectional study of 586 Iranian schoolchildren aged 12–14 years. The average load carried by schoolchildren was 2.8 kg. Neck, shoulder and low back complaints during the preceding month were reported by 35.3%, 26.1% and 33% of the students, respectively. Gender was an independent factor predicting musculoskeletal symptoms in schoolchildren. Girls were more likely than boys to suffer from neck, shoulder and low back complaints, although there was no significant difference between genders in terms of schoolbag carriage variables. The findings suggest that the recommended weight limit for schoolbag carriage may need to differ between boys and girls. The associations between schoolbag variables and reported symptoms are also discussed. The results provide evidence that the current weight limit should consider a broader combination of factors that influence the use of schoolbags.     

Efficient thermal desalination technologies with renewable energy systems: A state-of-the-art review

Due to the current fossil fuel crisis and associated adverse environmental impacts, renewable energy sources (RES) have drawn interest as alternatives to fossil fuels for powering water desalination systems. Over the last few decades the utility of renewable energy sources such as solar, geothermal, and wind to run desalination processes has been explored. However, the expansion of these technologies to larger scales is hampered by techno-economic and thermo-economic challenges. This paper reviews the state-of-the-art in the field of renewable energy-powered thermal desalination systems (RE-PTD) to compare their productivity and efficiency through thermodynamic, economic, and environmental analyses. We performed a comparative study using published data to classify RE-PTD systems technologies on the basis of the energy collection systems that they use. Among RE-PTD systems, solar energy powered-thermal desalination systems demonstrate high thermo-environ-economic efficiency to produce fresh water to meet various scales of demand.     

Dominant Enterobacteriaceae in tempeh were primarily originated from soybean

Food Science and Biotechnology - During tempeh production, boiling was considered as heat treatment that could significantly reduce or eliminate bacterial population in soybean before fungal...